You need 8 $ e^- $ to fill your shell
Exceptions to the Octet Rule
- Some only need 6
- Al and B
- Some only need 2
- H and He
- Some can have 12
- 3rd period
- $ SF_6 $ , S has 12
- $ PCl_5 $ , P has 10
- Pretty common actually
- Odd number of electrons
- These shouldn’t even exist really but other rules make it so they do ig
- NO
Chatgpted drawn out explanation:
The octet rule states that atoms tend to gain, lose, or share electrons to achieve a stable configuration with eight electrons in their valence shell. While a useful guideline, there are notable exceptions to this rule.
1. Incomplete Octet
- Elements: Group 2 and 3 elements (Be, B, Al) often have fewer than eight electrons in their valence shell.
- Explanation: These elements have a low Electronegativity and readily form bonds by sharing electrons. However, they may not achieve a full octet due to their limited number of valence electrons.
- Example: Boron trifluoride ( $ BF_3 $ ). Boron has only three valence electrons, forming three bonds with fluorine atoms. This leaves boron with only six electrons in its valence shell.
2. Expanded Octet
- Elements: Elements in Period 3 and beyond (from P to the right) can accommodate more than eight electrons in their valence shell.
- Explanation: These elements have available d orbitals in their valence shell, which can participate in bonding. This allows them to form more than four Covalent Bonds and expand their octet.
- Example: Sulfur hexafluoride ( $ SF_6 $ ). Sulfur has six valence electrons and forms six bonds with fluorine atoms. This results in 12 electrons around sulfur, exceeding the octet rule.
3. Odd Number of Electrons
- Elements: Elements with an odd number of valence electrons, such as nitrogen dioxide ( $ NO_2 $ ).
- Explanation: These molecules cannot achieve an even number of electrons around each atom, making it impossible for all atoms to have a complete octet.
- Example: Nitrogen dioxide ( $ NO_2 $ ). Nitrogen has five valence electrons, and oxygen has six. The molecule has a total of 17 valence electrons, resulting in an odd number of electrons around each atom.
4. Transition Metal Ions
- Elements: Transition metals often form ions with incomplete d-orbitals.
- Explanation: The d-orbitals are involved in bonding and can hold up to ten electrons. However, transition metal ions often have fewer than eight electrons in their valence shell, particularly in complex ions.
- Example: Copper(II) ion ( $ Cu^{2+} $ ). Copper has a d-orbital configuration of $ 3d^{10} $ in its neutral state. When it loses two electrons to form $ Cu^{2+} $ , it has a $ 3d^9 $ configuration. This configuration has only nine electrons in its valence shell.
Summary
The octet rule is a useful simplification but doesn’t always hold true. Understanding the exceptions to the octet rule is crucial for accurately predicting and explaining the behavior of molecules and ions.